Search results for "C–O bond formation"

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Screening of ligands for the Ullmann synthesis of electron-rich diaryl ethers

2012

In the search for new ligands for the Ullmann diaryl ether synthesis, permitting the coupling of electron-rich aryl bromides at relatively low temperatures, 56 structurally diverse multidentate ligands were screened in a model system that uses copper iodide in acetonitrile with potassium phosphate as the base. The ligands differed largely in their performance, but no privileged structural class could be identified.

chemistry.chemical_classificationC–O bond formationDenticityBase (chemistry)catalysisArylOrganic Chemistrynucleophilic aromatic substitutiondiaryl ethersUllmann-type couplingCombinatorial chemistryFull Research PaperCatalysislcsh:QD241-441Chemistrychemistry.chemical_compoundchemistrylcsh:Organic chemistryNucleophilic aromatic substitutionPotassium phosphateOrganic chemistrylcsh:QAcetonitrilelcsh:ScienceCopper iodideBeilstein Journal of Organic Chemistry
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